First Folia Occurrence From Greece

Georgios Lazaridis, Panagiotis Sotirios Dittopoulos

ABSTRACT:

Folia are among the rarest speleothems, known from 28 caves worldwide, and their origin is still a matter of ongoing scientific discussion and investigation. This study presents the first documented occurrence of folia in a Greek cave (Stafni Cave, Northern Greece), thus expanding the known geographical distribution and morphogenetic spectrum of these formations. The cave exhibits a morphologically complex setting with clear markers of water table oscillations, such as notches and cupolas, and unique depositional sequences that include folia, cave rafts, and associated pool infills. Notably, the folia occur stratigraphically beneath the rafts, suggesting progressive lowering of the water table. The folia deposit display classical “leaf-like” laminae. The preservation of these deposits below a thick layer of cave rafts that form a pseudo-floor suggests that their apparent rarity may reflect limited accessibility rather than true scarcity. Morphological features of the cave are consistent with speleogenetic models involving sulfuric acid speleogenesis (SAS), including sulfate mineral occurrences and proximity to active hydrogen sulfide-rich Na–Cl thermal springs. Folia morphology and formation are discussed. This study provides 3D documentation of a folia sample and lays the groundwork for future mineralogical and geochemical analyses aimed at testing these formation models. The findings contribute to ongoing debates on folia genesis and highlight the role of hypogene processes in cave evolution.

SIMPLE LANGUAGE SUMMARY:

Folia are a very rare kind of cave formation. They look like stacked, overlapping leaves or small shelves of mineral on cave walls, and they are known from only 28 caves in the whole world. Scientists still disagree about exactly how they form. This study reports the first folia ever found in Greece, in Stafni Cave in northern Greece. The cave shows clear signs that the water level inside it once rose and fell, such as notches cut into the walls and dome-shaped hollows in the ceiling. The folia lie underneath a thick layer of “cave rafts,” thin mineral sheets that form on the surface of still water and then sink. This order suggests that the water level in the cave slowly dropped over time. Because the folia were hidden under this layer, they may be more common than people think, just hard to reach and see. The cave seems to have been carved by acid that formed from hydrogen sulfide gas linked to nearby hot springs, rather than by ordinary rainwater. The authors also made a 3D model of a folia sample to help future studies of how folia form.

REFERENCES:

 

Audra, P., L. Mocochain, J. Y. Bigot, and J. C. Nobécourt, 2009, The association between bubble trails and folia: a morphological and sedimentary indicator of hypogenic speleogenesis by degassing, example from Adaouste Cave (Provence, France): International Journal of Speleology, v. 38, no. 2, p. 93–102, https://doi.org/10.5038/1827-806X.38.2.1
Arvanitis, A., E. Dotsika, and N. Kolios, 2017, Geochemical characteristics of the geothermal fluids in the Akropotamos area (Macedonia, Northern Greece): Bulletin of the Geological Society of Greece, v. 50, no. 2, p. 596–605, https://doi.org/10.12681/bgsg.11764
Davis, D. G., L. D. Hose, and H. R. DuChene, 2025, The taxonomy and origins of folia: a brief review: International Journal of Speleology, v. 54, no. 2, p. ijs2563, https://doi.org/10.5038/1827-806X.ijs2563
D’Angeli, I., C. Carbone, M. Nagostinis, M. Parise, M. Vattano, G. Madonia, and J. De Waele, 2018, New insights on secondary minerals from Italian sulfuric acid caves: International Journal of Speleology, v. 47, no. 3, p. 271–291, https://doi.org/10.5038/1827-806X.47.3.2175
D’Angeli, I. M., J. De Waele, O. C. Melendres, N. Tisato, F. Sauro, E. R. G. Gonzales, S. M. Bernasconi, S. Torriani, and T. R. Bontognali, 2015, Genesis of folia in a non-thermal epigenic cave (Matanzas, Cuba): Geomorphology, v. 228, p. 526–535, https://doi.org/10.1016/j.geomorph.2014.09.006
Davis, D. G., 2012, In defense of a fluctuating-interface, particle-accretion origin of folia: International Journal of Speleology, v. 41, no. 2, p. 189–198, https://doi.org/10.5038/1827-806X.41.2.6
Eleftheriadis, G., W. Frank, and K. Petrakakis, 2001, 40Ar/39Ar dating and cooling history of the Pangeon granitoids, Rhodope Massif (Eastern Macedonia, Greece): Bulletin of the Geological Society of Greece, v. 34, no. 3, p. 911–916.
Green, D. J., 1991, On the origin of the folia and rims: Salt Lake Grotto Technical Note, No. 88: Huntsville, Ala, National Speleological Society, p. 182–196.
Green, D. J., 1997, The origin of folia: Salt Lake Grotto Technical Note, No. 96: Huntsville, Ala, National Speleological Society, p. 51–60.
Häuselmann, P., 2011, UIS mapping grades: International Journal of Speleology, v. 40, no. 2, p. IV–VI.
Hill, C. A., and Forti, P., 1997, Cave Minerals of the World: Huntsville, Ala., National Speleological Society, p. 73–74.
Lazaridis, G., 2024, Formation conditions of hypogene caves in the Hellenic orogen: mineralogy, geochemistry, stable isotopes (C, O, S), fluid inclusions [Ph.D. thesis]: Thessaloniki, Aristotle University of Thessaloniki, Annex Number of Scientific Annals of the School of Geology No. 245, 165 p.
Lazaridis, G and K. Pipera, 2008, Preliminary report on granite caves in Greece: Cadernos do Laboratorio Xeolóxico de Laxe, v. 33, p. 101–113.
Lazaridis, G., 2017, Hypogene speleogenesis in Greece, in Klimchouk, A., Palmer, A. N., De Waele, J., Auler, A. S., and Audra, P., eds., Hypogene Karst Regions and Caves of the World: Cham, Springer, p. 225–239, https://doi.org/10.1007/978-3-319-53348-3_14
Lazaridis, G., K. P. Trimmis, I. Drnić, and K. Brkić Drnić, 2024, Deciphering rock surface origins in a karst cave: insights from the Rača Cave, Lastovo, Croatia: Geologia Croatica, v. 77, no. 3, p. 235–242.
Liñán Baena, C., C. Jiménez de Cisneros, Y. Del Rosal, and P. Forti, 2023, Reverse pseudo-gours: a new sub-type of folia observed in the Nerja Cave (SE Spain): International Journal of Speleology, v. 53, no. 1, p. 1–12, https://doi.org/10.5038/1827-806X.53.1.2485
López-Martínez, R., F. Gázquez, J. M. Calaforra, P. Audra, J. Y. Bigot, T. Pi Puig, R. J. Alcántara-Hernández, Á. Navarro, P. Crochet, L. Corona Martínez, and R. Daza Brunet, 2020, Bubble trail and folia in cenote Zapote, Mexico: petrographic evidence for abiotic precipitation driven by CO2 degassing below the water table: International Journal of Speleology, v. 49, no. 3, p. 173–186, https://doi.org/10.5038/1827-806X.49.3.2344
Plan, L and J. De Waele, 2011, Folia in der Odelsteinhöhle, Steiermark. Erstnachweis im deutschsprachigen Raum (Folia in Odelstein Cave, Styria first description from the German-speaking realm): Die Höhle, v. 62, p. 54–57.
Queen, M., 2009, The Lost City: hot springs, mixing and a possible model for folia development, in White, W. B., ed., 15th International Congress of Speleology, Proceedings, Volume 3, p. 1650–1656.
Ritter, S. M., M. Isenbeck-Schröter, C. Scholz, F. Keppler, J. Gescher, L. Klose, N. Schorndorf, J. Avilés Olguín, A. González-González, and W. Stinnesbeck, 2019, Subaqueous speleothems (Hells Bells) formed by the interplay of pelagic redoxcline biogeochemistry and specific hydraulic conditions in the El Zapote sinkhole, Yucatán Peninsula, Mexico: Biogeosciences, v. 16, no. 11, p. 2285–2305, https://doi.org/10.5194/bg-16-2285-2019
Webb, J. A., 2021, Supergene sulphuric acid speleogenesis and the origin of hypogene caves: evidence from the Northern Pennines, UK: Earth Surface Processes and Landforms, v. 46, no. 2, p. 455–464, https://doi.org/10.1002/esp.5037